4.6 Article

tBuOK-triggered bond formation reactions

Journal

RSC ADVANCES
Volume 9, Issue 41, Pages 24025-24029

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9ra04242c

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Funding

  1. National Natural Science Foundation of China [91845108]
  2. Natural Science Foundation of Jiangsu Province [Y81266JZQ3]
  3. National Program for Thousand Young Talents of China

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Recently, inexpensive and readily available tBuOK has seen widespread use in transition-metal-free reactions. Herein, we report the use of tBuOK for S-S, S-Se, NN and CN bond formations, which significantly extends the scope of tBuOK in chemical synthesis. Compared with traditional methods, we have realized mild and general methods for disulfide, azobenzenes imine etc. synthesis.

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