4.7 Article

Torsional chirality generation based on cyclic oligomers constructed from an odd number of pyrenes

Journal

CHEMICAL COMMUNICATIONS
Volume 55, Issue 65, Pages 9618-9621

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc03123e

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Funding

  1. Japan Society for the Promotion of Science (JSPS) KAKENHI Grant [JP18K14298, JP18K14190, JP17H03042, JP19H04584, JP26105004]

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A Ni(0)-mediated coupling reaction of a 1,8-dibromopyrene gave a series of cyclic pyrene oligomers CPn up to nonadecamer. CP5 and CP7 represent a unique class of asymmetric compounds with no stereogenic chiral centers in terms of their global chirality, which are achieved because of an odd number of pyrenes.

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