4.7 Article

Gold nanoparticles immobilized on single-layer α-zirconium phosphate nanosheets as a highly effective heterogeneous catalyst

Journal

ADVANCED COMPOSITES AND HYBRID MATERIALS
Volume 2, Issue 3, Pages 520-529

Publisher

SPRINGERNATURE
DOI: 10.1007/s42114-019-00091-x

Keywords

Zirconium phosphate; Gold nanoparticle; Catalysis; 4-nitrophenol reduction

Funding

  1. ACS Petroleum Research Fund [57580-ND5]
  2. National Science Foundation [CMMI-1562907]
  3. Natural Science Foundation of Jiangsu Province for Youth [BK20160960]
  4. 14th Six Talents Peak Project of Jiangsu Province [XNYQC-016]

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Gold nanoparticles (Au NPs) were immobilized on single-layered alpha -zirconium phosphate (ZrP) nanosheets as a highly efficient heterogeneous catalyst. The nanoparticles were characterized by thermogravimetric analysis (TGA), X-ray diffraction (XRD), X-ray photoelectric spectroscopy (XPS), UV-Vis spectroscopy, scanning electron microscopy (SEM), and transmission electron microscopy (TEM) techniques. The characterizations showed that the Au NPs with a size distribution of 2.01.0 nm were uniformly dispersed and immobilized on single-layer ZrP nanosheets. The supported AuNPs could serve as an effective catalyst for the reduction of 4-nitrophenol by sodium borohydride (NaBH4).

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