Journal
GREEN CHEMISTRY
Volume 21, Issue 16, Pages 4412-4421Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9gc01474h
Keywords
-
Funding
- National Key Technology RD Program [2016YFD040080]
- National Natural Science Foundation of China [21871019]
Ask authors/readers for more resources
An efficient electrochemical approach for the C(sp(2))-H phosphonation of quinoxalin-2(1H)-ones and C(sp(3))-H phosphonation of xanthenes has been developed. The chemistry was performed in an undivided cell under constant current conditions and features a wide range of substrates, up to 99% yield and it is free of transition-metal catalysts- and external oxidants, thereby providing a straightforward approach for dehydrogenative C-H/P-H cross-coupling. In addition, control experiments disclose that some of the reactions may involve a radical pathway.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available