4.3 Article

Activated carbon from the waste water purifier for supercapacitor application

Journal

JOURNAL OF SOLID STATE ELECTROCHEMISTRY
Volume 21, Issue 11, Pages 3169-3177

Publisher

SPRINGER
DOI: 10.1007/s10008-017-3653-9

Keywords

Activated carbon; Waste water purifier; KOH activation; Supercapacitor; Waste recycling

Funding

  1. Fundamental Research for the Central Universities of China [2013HGXJ0199, J2014HGXJ0092]
  2. Specialized Research Fund for the Doctoral Program of Higher Education [20120111120009]
  3. China Government 1000 Plan Talent Program
  4. China MOE NCET Program
  5. Natural Science Foundation of China [51322204]
  6. Fundamental Research Funds for the Central Universities [WK2060140014, WK2060140017]

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Activated carbon has been synthesized from the waste filter carbon in household water purifier. The original waste filter carbon (OFC) gives poor specific capacitance. However, the activated carbon SA-900-4 (OFC was heat treated at 900 degrees C to get SC-900, then SC-900 was activated by KOH with mass ratio of SC-900:KOH = 1:4 at 800 degrees C) shows great electrochemical performance. The SA-900-4 has a specific capacitance of 122.8 F g(-1) at current density of 1 A g(-1) in 1 M H2SO4 electrolyte. Furthermore, the specific capacitance of SA-900-4 is 93.8 F g(-1) at 10 A g(-1) and 78.1 F g(-1) at 20 A g(-1), nearly 76 and 63.6% of the value at 1 A g(-1), respectively, indicating good rate capacity of this activated carbon. In addition, the highest energy densities of 15.4 Wh kg(-1) in 1 M H2SO4 and 32.9 Wh kg(-1) in 1 M Na2SO4 were obtained respectively for the two-electrode supercapacitors based on SA-900-4. It is demonstrated that the waste filter carbon has the potential to be recycled as electrode material for electrochemical energy storage.

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