Journal
JOURNAL OF SOLID STATE ELECTROCHEMISTRY
Volume 21, Issue 8, Pages 2365-2371Publisher
SPRINGER
DOI: 10.1007/s10008-017-3584-5
Keywords
TiO2; SnO2; Nanotube; Triple-shell; Anode; Lithium-ion battery
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Funding
- National Research Foundation of Korea (NRF) - Ministry of Science, ICT, and Future Planning (MSIP) [NRF-2015R1A5A1037627]
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TiO2@SnO2@TiO2 triple-shell nanotubes are fabricated using electrospun polyacrylonitrile (PAN) nanofiber template and plasma-enhanced atomic layer deposition (PEALD). The triple-shell nanotubes have a uniform diameter of similar to 200 nm, and the thickness of each shell is similar to 10 nm. The triple-shell nanotube electrode exhibits high reversible capacity of 550 mA g(-1) after 60 cycles at the current density of 50 mA g(-1), stable cyclability, and high-rate performance (296 mA g(-1) at high current density of 5 A g(-1)) as an anode for lithium-ion batteries. The excellent electrochemical properties are attributed to the structural robustness of the triple-shell nanotubes against pulverization.
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