Journal
JOURNAL OF SOLID STATE CHEMISTRY
Volume 246, Issue -, Pages 341-345Publisher
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jssc.2016.12.003
Keywords
Lanthanide metal-organic frameworks; High-temperature sensing; Ratiometric; Luminescent thermometer
Funding
- National Natural Science Foundation of China [51472217, 51432001]
- Zhejiang Provincial Natural Science Foundation of China [LR13E020001, LZ15E020001]
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Temperature measurements and thermal mapping using luminescent MOF operating in the high-temperature range are of great interest in the micro-electronic diagnosis. In this paper, we report a thermostable Eu/Tb-mixed MOF Eu0.37Tb0.63-BTC-a exhibiting strong luminescence at elevated temperature, which can serve as a ratiometric luminescent thermometer for high-temperature range. The high-temperature operating range (313-473 K), high relative sensitivity and accurate temperature resolution, make such a Eu/Tb-mixed MOF useful for micro-electronic diagnosis.
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