4.7 Article

Phenolic hydrogen bond donors in the formation of non-ionic deep eutectic solvents: the quest for type V DES

Journal

CHEMICAL COMMUNICATIONS
Volume 55, Issue 69, Pages 10253-10256

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc04846d

Keywords

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Funding

  1. FCT/MCTES (PIDDAC) [POCI-01-0145-FEDER-007679, FCT UID/CTM/50011/2019, POCI-01-0145-FEDER-006984, FCT UID/EQU/50020/2019, POCI-01-0145-FEDER-016403]
  2. FEDER under the PT2020 Partnership Agreement

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Mixtures of non-ionic compounds have been reported as DES but most are just ideal mixtures. In the thymol-menthol system, an abnormal strong interaction was identified stemming from the acidity difference of the phenolic and aliphatic hydroxyl groups. This type of interaction is found to be the key to prepare non-ionic DES, that may be classified as type V.

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