Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 7, Issue 34, Pages 19898-19908Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9ta06199a
Keywords
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Funding
- National Key Research and Development Program of China [2017YFA0402902]
- National Natural Science Foundation Committee of China Academy of Engineering Physics (NSAF) [U1630108]
- USTC Center for Micro- and Nanoscale Research and Fabrication
- Shenzhen DRC project [[2018]1433]
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In recent years, although there has been great progress in the exploration of high capacity alkali metal ion batteries, the design of high-durable anode materials with high power density remains challenging. In this study, a flexible three-dimensional network of WSe2/C is reported as a dual-role anode for lithium/sodium ion batteries, providing multichannels for the fast lithium/sodium ion diffusion and a buffer matrix to restrain the volume change as well as increase the electron conductivity. The in situ transmission electron microscopy characterizations reveal a minor volume expansion of the WSe2/C (similar to 8.2%) and a complete-amorphization event occurring after the first lithiation process. WSe2/C exhibited superior reversible capacity/rate capability/cycling stability in lithium/sodium ion batteries. Particularly, a large stable capacity and ultra-long cycling life at ultra-high rate (257.0 mA h g(-1) at 25 A g(-1) after 10 000 cycles) are achieved for the WSe2/C electrode in lithium ion batteries, accompanied by only 0.5% capacity loss per cycle over 1000 cycles, which reveals its excellent capacity stability at ultra-high rates. This study reveals the great potential of WSe2/C as a high-capacity dual-role anode for lithium/sodium ions batteries.
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