4.7 Article

A supramolecular approach of modified polyoxometalate polymerization and visualization of a single polymer chain

Journal

CHEMICAL COMMUNICATIONS
Volume 55, Issue 72, Pages 10788-10791

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc05056f

Keywords

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Funding

  1. NSFC [21574057, 21773090]
  2. Changbaishan Distinguished Professor Funding of Jilin Province
  3. Program for JLU Science and Technology Innovative Research Team [2017TD-10]

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An anthracene modified Anderson-Evans polyoxometalate was polymerized via supramolecular inclusion and then covalent coupling with the support of gamma-cyclodextrin (gamma-CD) under UV light irradiation. The formed main chain polymers of the inorganic polyanions self-assembled into fibrous bundles and single-strand chains were visualized and characterized via TEM and other techniques.

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