Influence of synthesis temperatures on the crystalline grain growth and morphology of lanthanum magnesium hexaaluminate

Lanthanum magnesium hexaaluminate (LaMgAl11O19, LMA) was prepared at different temperatures by solid-state reaction. Phase compositions and crystal morphologies of specimens synthesized at different temperatures were investigated using X-ray diffraction (XRD), scanning electron microscopy (SEM). It was observed that the crystalline grain size of LMA was not only dependent on the preparation temperature but also on its powder morphology. In the temperature range of 1300-1550 degrees C, LMA showed platelet grain and the average crystalline grain size increases with the increase in temperature. At 1600 degrees C, if the powder was sintered for two times, the equiaxed grain could be found with the decrease in grain space, resulting in the reduction of the crystalline grain size. Styles of specimens (powder or disk) might have no obvious influence on morphologies and sizes of LMA crystalline grains which were synthesized with the well-dispersed raw material mixtures. The synthesis temperature played a key role in influencing the free space for the formation and growth of crystalline grains. (c) 2017 Chinese Society of Rare Earths. Published by Elsevier B.V. All rights reserved.