4.7 Article

Pd-CNT-SiO2 nanoskein: composite structure design for formic acid dehydrogenation

Journal

CHEMICAL COMMUNICATIONS
Volume 55, Issue 72, Pages 10733-10736

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc04593g

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Funding

  1. University of Waterloo
  2. NSERC
  3. CFI
  4. MINECO-Spain [CTM2017-84050-R]
  5. Xunta de Galicia [IN607A 2018/5]
  6. Xunta de Galicia (Centro Singular de Investigacion de Galicia, Acc. 2016-2019)

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High energy density and low toxicity of formic acid makes it a promising hydrogen energy carrier. Here we report a Pd/CNT-based formic acid dehydrogenation catalyst that shows a significant decrease in the apparent activation energy compared to benchmark Pd catalysts and provide a mechanistic insight into its catalytic performance.

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