Journal
CHEMICAL COMMUNICATIONS
Volume 55, Issue 72, Pages 10709-10712Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc05739k
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Funding
- Deutsche Forschungsgemeinschaft (DFG) [TA 189/9-2, TA 189/16-1]
- Fonds der Chemischen Industrie (FCI)
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The reaction of the phosphorus and arsenic dihalides (WCA-IDipp)ECl2 (E = P, As) that bear an anionic N-heterocyclic carbene ligand with a weakly coordinating borate moiety (WCA = B(C6F5)(3), IDipp = 1,3-bis(2,6-diisopropylphenyl)imidazolin-2-ylidene) with (IDipp)PSiMe3 afforded the monochlorides (WCA-IDipp)E(Cl)P(IDipp), which can be transformed into the cationic dipnictenes [(WCA-IDipp)EP(IDipp)][GaCl4] or neutral radicals [(WCA-IDipp)EP(IDipp)] by treatment with GaCl3 or reduction with 1,4-bis(trimethylsilyl)-1,4-dihydropyrazine.
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