Journal
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
Volume 313, Issue 1, Pages 175-189Publisher
SPRINGER
DOI: 10.1007/s10967-017-5274-2
Keywords
Uranium; Adsorption; Graphene oxide; Phosphorylation
Funding
- National Natural Science Foundation of China [21301028, 11475044, 41461070, 21561002]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT13054]
- Science & Technology Support Program of Jiangxi Province [20141BBG70001, 20151BBG70010]
- Advanced Science & Technology Innovation Team Program of Jiangxi Province [20142BCB24006]
- Innovation Team Program of Jiangxi Provincial Department of Science and Technology [2014BCB24006]
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The graphene oxide (GO) was functionalized with phosphate groups and applied as an effective adsorbent for the removal of uranium from aqueous solutions under various environmental conditions (e.g., solution pH, ions strength, contact time and temperature). Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy have confirmed that the phosphorylate group was successfully introduced on the surface of GO. The adsorption experiments indicated that the monolayer adsorption capacity has been increased from 249.38 mg/g (GO) to 336.70 mg/g [phosphorylated graphene oxide (PGO)] calculated by Langmuir model. Moreover, the adsorptive selectivity coefficients S (U(VI)/M(x)) increase from 42.43 to 51.96% after functionalized with phosphate group. The mechanism of U(VI) absorbed on PGO surface was dominated by surface complexation and electrostatic interaction. The results demonstrate that PGO will be a promising material for the efficient removal of U(VI) in the environment pollution remediation.
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