Journal
ENERGY STORAGE MATERIALS
Volume 21, Issue -, Pages 85-96Publisher
ELSEVIER
DOI: 10.1016/j.ensm.2019.06.028
Keywords
Polymer electrolyte; Poly(ethylene oxide); Sodium-ion battery; Conductivity; Mechanical robustness
Funding
- Office of Electricity Delivery and Reliability, Department of Energy
- Laboratory Directed Research and Development Program of Oak Ridge National Laboratory
- U.S. Department of Energy, Office of Science, Basic Energy Sciences, Materials Sciences and Engineering Division
- DOE BER
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Sodium-based energy storage systems are promising candidates for electric vehicles and grid-level energy storage applications. The advancement of sodium-based energy storage systems relies on the development of high performance sodium-ion conducting electrolytes and membranes that exhibit high ionic conductivity and mechanical stability. A crosslinked poly(ethylene oxide) based polymer electrolyte was developed that demonstrates high ionic conductivity, as well as excellent mechanical stability over a wide temperature range. Ionic conductivities up to 2.0 x 10(-4) S/cm at 20 degrees C and 7.1 x 10(-4) S/cm at 70 degrees C are achieved for the plasticized membrane, almost four orders of magnitude greater than that of the non-plasticized membrane. The membranes are mechanically robust, and the storage modulus of the membrane is maintained at similar to 1 MPa from -20 to 180 degrees C even with the addition of plasticizer. This study provides a synthesis approach towards the design of highly ion conducting, mechanically robust gel polymer electrolytes for Na-ion batteries, non-aqueous flow batteries, and many other applications.
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