Journal
JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER
Volume 201, Issue -, Pages 94-103Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.jqsrt.2017.06.032
Keywords
Acetylene; High temperature; Spectral line parameters; Databank; Radiative properties
Categories
Funding
- Russian Science Foundation [17-12-01204]
- Russian Science Foundation [17-12-01204] Funding Source: Russian Science Foundation
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We present a high-resolution, high-temperature version of the Acetylene Spectroscopic Databank called ASD-1000. The databank contains the line parameters (position, intensity, Einstein coefficient for spontaneous emission, term value of the lower states, self- and air-broadening coefficients, temperature dependence exponents of the self- and air-broadening coefficients) of the principal isotopologue of C2H2. The reference temperature for line intensity is 296K and the intensity cutoff is 10(-27) cm(-1)/(molecule cm(-2)) at 1000 K. The databank has 33,890,981 entries and covers the 3-10,000 cm(-1) spectral range. The databank is based on the global modeling of the line positions and intensities performed within the framework of the method of effective operators. The parameters of the effective Hamiltonian and the effective dipole moment operator have been fitted to the observed values of the line positions and intensities collected from the literature. The broadening coefficients as well as their temperature dependence exponents were calculated using the empirical equations. The databank is useful for studying high-temperature radiative properties of C2H2. ASD-1000 is freely accessible via the Internet site of V.E. Zuev Institute of Atmospheric Optics SB RAS ftp://ftpiao.ruipub/ASD1000/. (C) 2017 Published by Elsevier Ltd.
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