Journal
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 21, Issue 35, Pages 18816-18822Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cp01884k
Keywords
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Funding
- Ministry of Education Culture, Sports, Science and Technology (MEXT), Japan, program Elements Strategy Initiative to Form Core Research Center''
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Ni-Cu alloy supported on gamma-Al2O3 catalysts prepared by high-temperature hydrogen reduction exhibit high catalytic activity and durability for a three-way catalytic reaction under both oxidative and reductive conditions because of their self-regenerating feature. DFT calculations showed that Ni-oxide was reduced to Ni metal by CO in the presence of Cu metal because of the Ni-Cu alloy effect but was not in the absence of Cu metal.
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