Journal
CHEMICAL COMMUNICATIONS
Volume 55, Issue 75, Pages 11168-11170Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc05097c
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Funding
- Centre National de la Recherche Scientifique (CNRS), Aix-Marseille Universite
- Centrale Marseille
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Vinylidene-quinone methides (VQMs) are highly electrophilic chiral reagents that can be generated in situ from 2-(phenylethynyl)phenols. They were characterized for the first time in 2012 but their enantioselective organocatalytic activation was addressed only very recently. Their specific reactivity has revealed innovative strategies notably for the control of axial chirality.
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