Journal
ISCIENCE
Volume 19, Issue -, Pages 597-+Publisher
CELL PRESS
DOI: 10.1016/j.isci.2019.08.013
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Funding
- National Science Foundation of China [51472088, 51602104, 51603069, U1601205]
- Natural Science Foundation of Guangdong Province, China [2016A030310432, 2017A030313287]
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The development of luminescence materials with long-lived upconversion (UC) phosphorescence and long luminescence rise edge (LRE) is a great challenge to advance the technology of photonics and materials sciences. The lanthanide ions-doped UC materials normally possess limited UC lifetime and short LRE, restricting direct afterglow viewing in visual images by the naked eye. Here, we show that the RbCaF3:Mn2+,Yb3+ UC luminescence material generates a long UC lifetime of similar to 62 ms peaking at 565 nm and an ultralong LRE of similar to 5.2ms. Density functional theory calculations provide a theoretical understanding of the Mn2+-Yb3+ aggregation in the high-symmetry RbCaF3 host lattice that enables the formation of the long-lived UC emission center, superexchange coupled Yb3+-Mn2+ pair. Through screen printing ink containing RbCaF3:Mn2+,Yb3+, the visualized multiple anti-counterfeiting application and information encryption prototype with high-throughput rate of authentication and decryption are demonstrated by the dynamic color separation effect.
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