Journal
CHEMICAL COMMUNICATIONS
Volume 55, Issue 73, Pages 10848-10851Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc04977k
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Funding
- National Natural Science Foundation of China [21801163, 21702213, 51673113]
- STU Scientific Research Foundation for Talents [NTF18003]
- Key Project of DEGP [2018KZDXM032]
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A simple, mild and efficient approach to access fluorinated dibenz[b,e]azepines via visible-light photoredox catalysis is presented. Inexpensive and commercially available fluoroalkyl anhydrides in concert with pyridine N-oxide are employed as the source of the fluoroalkyl radicals. A one-pot process involving the trifluoroacetylation of unprotected secondary benzyl amines followed by radical cyclization could also afford the desired fluorinated dibenz[b,e]azepines.
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