4.7 Article

Design of cost-efficient and photocatalytically active Zn-based MOFs decorated with Cu2O nanoparticles for CO2 methanation

Journal

CHEMICAL COMMUNICATIONS
Volume 55, Issue 73, Pages 10932-10935

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc04446a

Keywords

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Funding

  1. European Union [ERC-2016-CoG 724681-S-CAGE]
  2. Spanish MICINN (Structures of Excellence Maria de Maeztu) [MDM-2015-0538]
  3. Spanish MICINN (Severo Ochoa) [SEV-2016-0683, CTQ2017-89528-P, RTI2018-098237-B-C21, RTI2018-099482-A-I00, PGC2018-102052-B-C21]
  4. Generalitat Valenciana [Prometeo 2017-083]
  5. Junta de Andalucia [P12-FQM-1484]
  6. MICINN
  7. Research Executive Agency (REA) [709023/ZESMO]
  8. European Commission [709023/ZESMO]

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Here we show for the first time a MOF that is photocatalytically active for light-assisted CO2 methanation under mild conditions (215 degrees C) without the inclusion of metallic nanoparticles or any sacrificial agent. The presence of Cu2O nanoparticles causes a 50% increase in the photocatalytic activity. This result paves the way for developing efficient and cost-effective materials for CO2 elimination.

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