4.8 Article

Prussian blue nanocubes as cathode materials for aqueous Na-Zn hybrid batteries

Journal

JOURNAL OF POWER SOURCES
Volume 355, Issue -, Pages 18-22

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2017.04.049

Keywords

Hybrid aqueous batteries; Prussian blue; Single iron-source; Cycling stability; Rate capability

Funding

  1. Ministry of Science and Technology of the People's Republic of China [2016YFA0202503]
  2. National Natural Science Foundation of China [51672281, 21403243]
  3. National Basic Research Program [2012CB932901]

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Rechargeable aqueous battery is very attractive as a promising alternative energy storage system, based on its safety and environmental-friendly properties. An aqueous rechargeable Na-Zn hybrid battery is assembled by using Prussian blue nanocubes and metallic zinc as cathode and anode, respectively. This Na-Zn cell delivers a high specific capacity of 73.5 mA h g(-1) and a good cycling stability (ca. 80% capacity retention after 1000 cycles at 300 mA g(-1)) due to the impressive structure stability of Prussian blue nanocubes. These remarkable features are realized by a simple synthetic method and a feasible battery manufacturing process, which can provide guidance for the development of rechargeable batteries in a large scale. (C) 2017 Elsevier B.V. All rights reserved.

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