4.8 Article

Aluminum anode for aluminum-air battery - Part II: Influence of In addition on the electrochemical characteristics of Al-Zn alloy in alkaline solution

Journal

JOURNAL OF POWER SOURCES
Volume 357, Issue -, Pages 47-55

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2017.04.097

Keywords

Aluminum-air battery; Anode; Aluminum alloy; Discharge performance; Battery resistance

Funding

  1. National Research Foundation of Korea (NRF) grant - Korea Government (Ministry of Education, Science and Technology) [NRF-2016R1A2B4016027]

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Effects of Zn and In additions on the aluminum anode for Al-air battery in alkaline solution are examined by the self-corrosion rate, cell voltage, current-voltage characteristics, anodic polarization, discharge performance and AC impedance measurements. The passivation behavior of Zn-added anode during anodic polarization decreases the discharge performance of Al-air battery. The addition of In to Al-Zn anode reduces the formation of Zn passivation film by repeated adsorption and desorption behavior of In ion onto anode surface. The attenuated Zn passive layer by In ion attack leads to the improvement of discharge performance of Al-air battery. (C) 2017 Elsevier B.V. All rights reserved.

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