Journal
JOURNAL OF POWER SOURCES
Volume 364, Issue -, Pages 215-225Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2017.08.015
Keywords
Pt-Ir alloy catalyst; Reduced graphene oxide; Spray pyrolysis; Post heat treatment; Unitized regenerative fuel cells
Funding
- National Research Foundation of Korea [NRF-2016R1D1A1B03934747]
- KIST [2E27061, 2E27301-17-033]
- Kwangwoon University
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Three-dimensional (3D) crumpled reduced graphene oxide supported Pt-Ir alloys that served as bifunctional oxygen catalysts for use in untized regenerative fuel cells were synthesized by a facile spray pyrolysis method. Pt-Ir catalysts supported on rGO (Pt-Ir/rG0s) were physically characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and thermogravimetric analysis (TGA) to observe change in composition by heat treatment, alloying, and morphological transition of the catalysts. Their catalytic activities and stabilities for the oxygen reduction reaction (ORR) and the oxygen evolution reaction (OER) conditions were electrochemically investigated using cyclic voltammetry (CV), linear sweep voltammetry (LSV), potential cycling and hold tests on the rotating disk electrode (RDE). Pt-Ir/rGO with no post heat treatment (Pt-Ir/rGO_NP) showed a lower activity for ORR and OER although metal nanoparticles decorated on the support are relatively small. However, Pt-Ir/rGO showed remarkably enhanced activity following heat treatment, depending on temperature. Pt-Ir/rGO heat-treated at 600 degrees C after spray pyrolysis (Pt-Ir/rGO_P600) exhibited a higher activity and stability than a commercially available Pt/C catalyst kept under the ORR condition, and it also revealed a comparable OER activity and durability versus the commercial unsupported Ir catalyst. (C) 2017 Elsevier B.V. All rights reserved.
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