Journal
JOURNAL OF POWER SOURCES
Volume 345, Issue -, Pages 146-155Publisher
ELSEVIER
DOI: 10.1016/j.jpowsour.2017.02.011
Keywords
Graphene hydrogels; Co-doped; Hierarchical porous; pH values; Binder-free; Supercapacitors
Funding
- Guangdong and Shenzhen Innovative Research Team Program [2011D052, KYPT20121228160843692]
- R&D Funds for basic Research Program of Shenzhen [JCYJ20150401145529012, JCYJ20140418095735619]
- Shenzhen Fundamental Research Program [JCYJ20160331191741738, JSGG20160229194437896]
- Key Deployment Project of Chinese Academy of Sciences [KFZD-SW202]
- Natural Science Foundation of Guangdong [2015A030310087]
- NSFC-Guangdong Jointed Funding [U1601202]
- NSFC-Shenzhen Robot jointed Funding [U1613215]
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Nitrogen/sulfur co-doped and hierarchical porous graphene hydrogels (DHGHs) are prepared by facile self-assembly process. The results show that the pH values of preparation process significantly affect the microstructures and electrochemical properties of DHGHs and the mechanism has been discussed. The as-prepared DHGHs can be directly used as binder-free electrodes to assemble full-cell supercapacitor devices. It is surprising that the DHGHs prepared at basic condition (DHGH-12) delivers a specific capacitance of 251 F g(-1) (0.5 A g(-1)). Moreover, the DHGH-12 shows rectangular cyclic voltammetry shape at a high scan rate of 3000 mV s(-1) and symmetrical galvanostatic charge/discharge curves at 100 A g(-1) which exhibits a specific capacitance of 136.5 F g(-1), a high energy density of 4.74 Wh kg(-1) and high power density of 25.47 kW kg(-I). Additionally, DHGH-12 presents superior cycling stability (96.8% retention after 2000 cycles at 20 A g(-1)) in 6 M ICOH solution. Therefore, the novel DHGHs can be considered as promising candidate for high energy density supercapacitors at high rates. (C) 2017 Elsevier B.V. All rights reserved.
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