Journal
CATALYSIS IN INDUSTRY
Volume 11, Issue 3, Pages 179-190Publisher
MAIK NAUKA-INTERPERIODICA
DOI: 10.1134/S2070050419030097
Keywords
oxidation catalysts; trimethyl-p-benzoquinone; vitamin E; heteropolyacids
Categories
Funding
- state task for the Boreskov Institute of Catalysis [AAAA-A17-117041710081-1]
Ask authors/readers for more resources
Different ways of preparing 2,3,5-trimethyl-1,4-benzoquinone (TMQ), a key intermediate in the synthesis of vitamin E, via the catalytic oxidation of 2,3,6-trimethylphenol (TMP) are considered. It is shown that aqueous solutions of Mo-V phosphoric heteropolyacids (HPAs) are promising catalysts for the oxidation of TMP with oxygen. Different technological options are analyzed for using HPAs in this reaction: the one-stage homogeneous acetic acid oxidation of TMP and a biphasic two-step procedure. The efficiency of a biphasic version that ensures high (up to 99.5%) selectivity for TMQ and high catalyst productivity in the target reaction (approximate to 600-800 g TMQ L-cat(-1) h(-1)) is proved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available