Journal
JOURNAL OF PHYSICAL ORGANIC CHEMISTRY
Volume 30, Issue 9, Pages -Publisher
WILEY
DOI: 10.1002/poc.3738
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Funding
- NSF [CHE-1465075]
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Bromination of the widely used triplet sensitizer thioxanthone extends the absorption spectrum into the visible range with only minor loss of lowest triplet state energy (3 kcal/mol for di-bromination). Because of bromine substitution, a slight increase in triplet quantum yield was observed. The di-brominated derivative was effective as organo-photocatalyst in performing [2 + 2] cross-photocycloaddition of acrylimide-based compounds under visible light irradiation.
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