Journal
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
Volume 8, Issue 9, Pages 1952-1955Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpclett.7b00583
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Funding
- National Science Foundation [CHE-1409698]
- Welch Foundation [C-0807]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1409698] Funding Source: National Science Foundation
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The selective interactions between short oligomers of single-stranded DNA (ssDNA) and specific structures of single-walled carbon nanotubes have been exploited in powerful methods for nanotube sorting. We report here that nanotubes coated with ssDNA also display selective interactions through the selective quenching of nanotube fluorescence by dissolved oxygen. In aqueous solutions equilibrated under I atm of O-2, emission intensity from semiconducting nanotubes is reduced by between 9 and 40%, varying with the combination of ssDNA sequence and nanotube structure. This quenching reverses promptly and completely on the removal of dissolved 02 and may be due to physisorption on nanotube surfaces. Fluorescence quenching offers a simple, nondestructive approach for studying the structure-selective interactions of ssDNA with single walled carbon nanotubes and identifying recognition sequences.
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