Journal
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
Volume 8, Issue 7, Pages 1569-1573Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpclett.7b00457
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- Deutsche Forschungsgemeinschaft (DFG) [Sonderforschungsbereich 677]
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Spin-crossover molecules on metallic substrates have recently attracted considerable interest for their potential applications in molecular spintronics. Using scanning tunneling microscopy, we evidence the first successful deposition of a charged Fe-III spin-crossover complex, [Fe(pap)(2)](+) (pap = N-2-pyridylmethylidene-2-hydroxyphenylaminato), on Au(111). Furthermore, the bulk form of the molecules is stabilized by a perchlorate counterion, which depending on the deposition technique may affect the quality of the deposition and the measurements. Finally, we evidence switching of the molecules on Au(111).
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