Journal
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
Volume 8, Issue 19, Pages 4820-4825Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpclett.7b01927
Keywords
-
Categories
Funding
- BMW AG
- BASF SE
- TUM-IAS
Ask authors/readers for more resources
We compare the stability of alkyl carbonate electrolyte on NMC111, -622, and -811, LNMO, and conductive carbon electrodes. We prove that CO, and CO evolution onset potentials depend on the electrode material and increase in the order NMC811 < NMC111 approximate to NMC622 < conductive carbon approximate to LNMO, which we rationalize by two fundamentally different oxidation mechanisms, the chemical and the electrochemical electrolyte oxidation. Additionally, in contrast to the widespread understanding that transition metals in cathode active materials catalyze the electrolyte oxidation, we will prove that such a catalytic effect on the electrochemical electrolyte oxidation does not exist.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available