Journal
MATERIALS CHEMISTRY FRONTIERS
Volume 3, Issue 10, Pages 2066-2071Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9qm00358d
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Funding
- National Natural Science Foundation of China [21702180]
- Jiangsu Provincial Nature Science Foundation [SBK2016021885]
- Top-notch Academic Programs Project of Jiangsu Higher Education Institutions
- Priority Academic Program Development of Jiangsu Higher Education Institutions
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Four chiral AIE-active luminogens (AIEgens) containing tetraphenylethene (TPE) and one or two chiral glutamic moieties connected by thiourea were designed and synthesized. All AIEgens showed tunable aggregation-induced circularly polarized luminescence (AICPL) by adjusting the mono-/di-substituents of molecules or nanostructures of self-assemblies. The enantiotopic mono-substituted compounds (TPE-Glu) exhibited mirror-imaged AICPL signals with the maximal |g(lum)| value of up to 0.02. Interestingly, the di-substituted cis- and trans-isomers showed reverse AICPL signals compared with those of mono-substituted ones. cis- and trans-isomers (TPE-DGlu) showed similar AICPL properties, whose signs of AICPL signals reversed while the water fraction (f(w)) was more than 80%. The SEM images of their self-assemblies indicated that the AICPL properties should have an intrinsic relation with their molecular structures or self-assembled nanostructures.
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