Journal
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
Volume 8, Issue 4, Pages 844-849Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpclett.6b03045
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Funding
- Ministry of Education, Culture, Sports, Science and Technology (MEXT) of the Japanese Government [25220806]
- JSPS [P15073]
- Grants-in-Aid for Scientific Research [15F15073] Funding Source: KAKEN
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Two-dimensional Au-nanoprism/reduced graphene oxide (rGO)/Pt-nanoframe was synthesized as plasmonic photocatalyt, exhibiting activity of photocatalytic hydrogen generation greater than those of Au-nanorod/rGO/Pt-nanoframe and metallic plasmonic photocatalyst Pt-Au. The, single-particle plasmonic photoluminescence study demonstrated that Au-nanorod has only a longitudinal plasmon resonance mode for hot electron transfer to rGO, while Au-nanoprism has in-plane dipole and multipole surface plasmon resonance modes for hot electron transfer, leading to highly efficient charge separation for hydrogen generation.
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