Journal
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
Volume 8, Issue 24, Pages 6029-6034Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpclett.7b02944
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Funding
- Fonds National Suisse de la Recherche Scientifique [200020-165890]
- University of Geneva
- Polish National Science Centre [MAESTRO 2012/06/A/ST5/00216]
- Foundation for Polish Science [TEAM/2016-3/22]
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The influence of the length of the push pull branches of quadrupolar molecules on their excited-state symmetry breaking was investigated using ultrafast time resolved IR spectroscopy. For this, the excited-state dynamics of an A-pi-D-pi-A molecule was compared with those of an ADA analogue, where the same electron donor (D) and acceptor (A) subunits are directly linked without a phenylethynyl pi-spacer. The spatial distribution of the excitation was visualized in real time by monitoring C equivalent to C and C equivalent to N vibrational modes localized in the spacer and acceptor units, respectively. In nonpolar solvents, the excited state is quadrupolar and the excitation is localized on the pi-D-pi center. In medium polarity solvents, the excitation spreads over the entire molecule but is no longer symmetric. Finally, in the most polar solvents, the excitation localizes on a single D-pi-A branch, contrary to the ADA analogue where symmetry breaking is only partial.
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