Journal
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
Volume 8, Issue 14, Pages 3415-3420Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpclett.7b01248
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Funding
- Rennes Metropole through the Allocation d'installation scientifique program
- EU H2020 Project [676598]
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The impact of surface deposition on cooperativity is explored in Au(111)-supported self-assembled metal-organic frameworks (MOFs) based on Fe(II) ions. Using a thermodynamic model, we first demonstrate that dimensionality reduction combined with deposition on a metal surface is likely to deeply enhance the spin-crossover cooperativity, going from gamma(3D) = 16 K for the bulk material to gamma(supp)(2D) = 386 K for its 2D supported derivative. On the basis of density functional theory, we then elucidate the electronic structure of a promising Fe-based MOF. A chemical strategy is proposed to turn a weakly interacting magnetic system into a strongly cooperative spin-crossover monolayer with gamma(Au(111))(MOF) = 83 K. These results open a promising route to the fabrication of cooperative materials based on SCO Fe(II) platforms.
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