4.6 Article

Nature-Mimic ZnO Nanoflowers Architecture: Chalcogenide Quantum Dots Coupling with ZnO/ZnTiO3 Nanoheterostructures for Efficient Photoelectrochemical Water Splitting

Journal

JOURNAL OF PHYSICAL CHEMISTRY C
Volume 121, Issue 39, Pages 21096-21104

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.jpcc.7b04701

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Funding

  1. National Science Foundation of China [51672003]

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We prepared novel photoanodes structured as FTO/ZnO nanoflowers/ZnTiO3/CdS/CdTeS/ZnS quantum dots (QDs) with highly exposed large specific area and energy coupling. The design of the photoanode expressed significant enhanced photoelectrochemical (PEC) performance such as improved absorption efficiency, reduced recombination rate, and enhanced charge transportation state, resulting in a significant increase in photoelectron current. The multi-nanoheterostructures photoanode provides a high photo catalytic activity and a maximum photocurrent density up to 9.41 mA/cm(2) under AM 1.5 G illumination. The novel cosensitized multinanoheterostructures photoanodes lead to a remarkable and promising application in photoelectrochemical and water splitting reactions.

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