Journal
CHEMICAL COMMUNICATIONS
Volume 55, Issue 78, Pages 11715-11718Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc05455c
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Funding
- National Natural Science Foundation of China [21825601, 21790374, 21806118]
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
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When exposed to UV (365 nm, 2 mW) radiation, the bulk crystals of a two-dimensional metal-organic framework [Hphen](2)[(UO2)(2)(ox)(3)] (1,phen = 1,10-phenanthroline, ox = oxalate) are exfoliated into thin sheets (2 mu m) and its photoluminescence can be quenched in an incredibly sensitive manner, setting 1 as a superior UV-detection material. When upgrading the UV source into a 300 W xenon light source, the crystals of 1 can be further exfoliated into monolayer nanosheets (0.92 nm).
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