Journal
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
Volume 339, Issue -, Pages 67-79Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jphotochem.2017.01.013
Keywords
Clay minerals; Dye/clay complex; Fluorescence enhancement; S-FIE; Stilbazolium; Porphyrin
Categories
Funding
- PRESTO/JST program, Innovative Use of Light and Materials/Life
- JSPS [144483221]
- Building of Consortia for the Development of Human Resources in Science and Technology, Ministry of Education, Culture, Sports, Science and Technology, Japan
- [24350100]
- [25107521]
- [2603441]
- Grants-in-Aid for Scientific Research [15K13291] Funding Source: KAKEN
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We have been investigating complexes composed of nano-sheet with anionic charges such as clay nanosheets and molecules such as cationic organic dyes. Photochemical properties of organic dyes are much affected by the complex formation with nano-sheet in many cases. Especially, a strong fluorescence enhancement behavior of dyes was frequently observed on the nano-sheet surface. Based on the mechanism, we name this unique effect S-Fixation Induced Emission (S-FIE). The examples for fluorescence enhancement are shown and the mechanism is discussed in detail. (C) 2017 Elsevier B.V. All rights reserved.
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