Journal
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
Volume 346, Issue -, Pages 221-224Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jphotochem.2017.06.008
Keywords
Push-pull chromophores; Photoluminescence; ICT state; Transient absorption
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Funding
- National Natural Science Foundation of China [21573094, 51502109, 11274142, 11674315, 11474131]
- Open Project of State Key Laboratory of Superhard Materials (Jilin University)
- National Found for Fostering Talents of Basic Science [J1103202]
- Science Challenging Program [JCICY2016212A501]
- Chinese Scholarship Council
- science and technology projects in the 13th Five-Year Plan in The Education Department of Jilin Province [2016-402]
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Two push-pull compounds, which are comprised of triphenylamine (TPA) (electron donor units) and functionalized beta-diketones difluorboron complexes (electron acceptor units) are probed by many spectroscopies, which offers the relationship between electron acceptor and the intrinsic excited state properties of push-pull chromophores. We found that the photoluminescence (PL) intensity would enhance with the number of electron acceptor. Transient absorption (TA) data shows that intramolecular charge transfer (ICT) process really exists in the two molecules after photoexcitation and this process would be prolonged through increasing the electron-acceptor, which would be responsible for the improvement of PL property. (C) 2017 Elsevier B.V. All rights reserved.
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