Journal
INTERNATIONAL JOURNAL OF AMBIENT ENERGY
Volume -, Issue -, Pages -Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/01430750.2019.1673818
Keywords
Isomeric chlorotoluene; charge-transfer complex; partial molar volume; PFP theory
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The densities (?), ultrasonic speeds (u), and viscosities (?) are reported for binary mixtures of o-chlorotoluene, m-chlorotoluene and p-chlorotoluene with 2-methoxy aniline at temperature range from (303.15?318.15) K and at a pressure p?=?0.1?MPa. In addition, excess functions such as excess molar volume, excess isentropic compressibility and deviation in viscosity are calculated from the density, speed of sound and viscosity and the Redlich?Kister equation, correlates these properties. The excess partial molar volumes, and , and excess partial molar isentropic compressibilities, and of the components at infinite dilution are calculated. As well, the calculated excess properties were discussed in terms of the influence of chlorine atom on interactions between halo hydrocarbons and 2-methoxy aniline. Moreover, the V-E values have been analysed with Prigogine-Flory-Patterson theory and shown that the free volume contribution is the supporting factor for negative values of excess molar quantities.
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