4.7 Article

Spin-crossover iron(ii) complex showing thermal hysteresis around room temperature with symmetry breaking and an unusually high T(LIESST) of 120 K

Journal

CHEMICAL COMMUNICATIONS
Volume 55, Issue 81, Pages 12227-12230

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc05988a

Keywords

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Funding

  1. EU (ERC) [MOL-2D 788222]
  2. Spanish MINECO
  3. FEDER funds [MAT-2017-89993-R, CTQ2017-89528-P]
  4. FEDER funds (Unidad de Excelencia Maria de Maeztu) [MDM-2015-0538]
  5. Generalitat Valenciana (PROMETEO program)

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We report a Fe(ii) complex based on 4 ',4 '' carboxylic acid disubstituted dipyrazolylpyridine that shows a spin-crossover close to room temperature associated to a crystallographic phase transition and the LIESST effect with a high T(LIESST) of 120 K.

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