Journal
MOLECULAR SYSTEMS DESIGN & ENGINEERING
Volume 4, Issue 5, Pages 995-999Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9me00060g
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Funding
- EPSRC through the Centre for Doctoral Training in Sustainable Chemistry [EP/L015633/1]
- EPSRC [EP/P002382/1]
- Leverhulme Trust [RPG-2016-442]
- University of Nottingham Propulsion Futures Beacon of Excellence
- Generalitat Valenciana [CIDEGENT/2018/036]
- EPSRC [EP/P002382/1, EP/S031170/1] Funding Source: UKRI
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Double-chain redox-active surfactants based on hybrid polyoxometalates show solvent-dependent assembly into nanoscale micellar architectures. These organic-inorganic hybrid amphiphiles, of the general formula K-6[P2W17O61(POC6H4O(CnH2n+1))(2)], were prepared with varying aliphatic chain lengths (n = 10, 12, 14, 16, 18 and 20) and display different multi-electron redox behaviours in their molecular and supramolecular forms. Furthermore, modification of the length of the hydrophobic tail is an effective strategy for controlling the stability and electronic properties of the supramolecular nanostructures.
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