4.7 Article

Palladium-mediated intramolecular dearomatization of ligated dialkylterphenyl phosphines

Journal

DALTON TRANSACTIONS
Volume 48, Issue 39, Pages 14575-14579

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9dt03201k

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Funding

  1. MICINN [CTQ2017-82893-C2-2-R]
  2. Universidad de Sevilla

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Aryl-Pd(II) chlorides stabilized by dialkylterphenyl phosphine ligands undergo a thermal isomerization process, leading to the formation of allyl-Pd(II)-chloride species. The transformation involves the intramolecular functionalization of a C-H bond of the terphenyl group mediated by the Pd(II) center.

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