4.7 Article

A rose bengal-functionalized porous organic polymer for carboxylative cyclization of propargyl alcohols with CO2

Journal

CHEMICAL COMMUNICATIONS
Volume 55, Issue 83, Pages 12475-12478

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc07043e

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Funding

  1. National Key Research and Development Program of China [2018YFB0605801]
  2. National Natural Science Foundation of China [21673256]
  3. Chinese Academy of Sciences [QYZDY-SSW-SLH013-2]
  4. Beijing Municipal Science & Technology Commission [Z181100004218004]

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A Rose bengal-functionalized porous organic polymer (RB-POP) was prepared with a specific surface area of up to 562 m(2) g(-1). In the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene, RB-POP supported Ag(0) nanoparticles exhibited excellent performance for catalyzing cyclization of propargyl alcohols with CO2 at 30 degrees C, achieving a TOF of 5000 h(-1), the highest value among the reported ones.

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