4.7 Article

Black/red phosphorus quantum dots for photocatalytic water splitting: from a type I heterostructure to a Z-scheme system

Journal

CHEMICAL COMMUNICATIONS
Volume 55, Issue 83, Pages 12531-12534

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc06146k

Keywords

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Funding

  1. Strategic Priority Research Program of the Chinese Academy of Sciences [XDB17000000]
  2. National Natural Science Foundation of China [21773275, 21971250, 21633015, 11721404]
  3. Ministry of Science and Technology [2018YFA0208701]
  4. K. C. Wong Education Foundation
  5. CAS-Croucher Funding Scheme for Joint Laboratories

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By virtue of the quantum confinement effect, the junction between black phosphorus and red phosphorus changes from a type I heterostructure for bulk materials to a Z-scheme system for quantum dots. The Z-scheme system of black/red phosphorus quantum dots (BP/RP-QD) achieves H-2 evolution from water splitting in the absence of sacrificial agents.

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