Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 849-850, Issue -, Pages 201-218Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2017.05.007
Keywords
Alkanes; Alcohols; Alkyl hydroperoxides; Hydrogen peroxide; meta-Chloroperoxybenzoic acid (MCPBA); Stereoselectivity
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Funding
- Russian Foundation for Basic Research [16-03-00254, 17-03-00993]
- Ministry of Education and Science of the Russian Federation [02.a03.21.0008]
- Plekhanov Russian University of Economics
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Polynuclear transition metal complexes in Si- or Ge-sesquioxane frameworks synthesized in recent years turned out to be efficient catalysts in oxidation of organic compounds with peroxides: H2O2, tert-butyl hydroperoxide (TBHP), meta-chloroperoxybenzoic acid (MCPBA). This brief review describes oxygenations by peroxides of alkanes to alkyl hydroperoxides, alcohols and ketones and benzene to phenol as well as oxidation of alcohols to the corresponding ketones. Some reactions with MCPBA occur stereoselectively. (C) 2017 Elsevier B.V. All rights reserved.
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