Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 82, Issue 5, Pages 2570-2578Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.6b02995
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- Ministerio de Economia y Competitividad, MINECO [CTQ2015-68380-R]
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The combination of a three-component, solvent-free pyrrole synthesis performed under mechanochemical conditions with a TMSOTf-catalyzed oxonium-mediated cyclization gave general access to pyrrolo[2,1-a]isoquinoline derivatives under very mild conditions. The structural diversity generated by this method was extended by the preparation of six additional unusual polyheterocyclic frameworks.
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