Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 82, Issue 9, Pages 4883-4890Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.7b00615
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Funding
- Science and Engineering Research Board [EMR-2015-43]
- Council of Scientific and Industrial Research [02(0255)/16/EMR-II]
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A copper-mediated picolinamide directed regioselective cross-coupling of naphthylamines with azoles is developed via C-H functionalization and C-N bond formation. The reaction of indoles leads to the formation of chiral C-N cross-coupled products with functional group tolerance. These reaction conditions can also be extended to the cross-coupling of pyrazole and pyrrole scaffolds.
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