4.7 Article

Rhodium(III)-Catalyzed C-H Activation of Nitrones and Annulative Coupling with Nitroalkenes

Journal

JOURNAL OF ORGANIC CHEMISTRY
Volume 82, Issue 18, Pages 9877-9884

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.7b01574

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Funding

  1. Henan Normal University [5101034011009]
  2. Dalian Institute of Chemical Physics (Chinese Academy of Sciences)

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Rh(III)-catalyzed synthesis of nitro-functionalized indenes has been realized via C-H activation of arylnitrones and annulation with nitroolefins. The reaction proceeded in moderate to high yields with good functional group tolerance under ambient atmosphere.

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