Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 82, Issue 23, Pages 12119-12127Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.7b01917
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Funding
- National Natural Science Foundation of China [21102134, 21172200]
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A mild and efficient protocol for C4-H sulfonylation of 1-naphthylamine derivatives with sodium sulfinates has been described. This C4 sulfonylation proceeded smoothly at room temperature under Ru/Cu photoredox catalysis or Cu/Ag cocatalysis and could tolerate various functional groups. In addition, control experiments suggested that this C4-H sulfonylation reaction might proceed via a single-electron-transfer process.
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