Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 82, Issue 7, Pages 3901-3907Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.6b03062
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Funding
- NSFC [21272057, 21372065, U1604285]
- Young Backbone Teachers Fund of Henan [2014GGJS-049]
- Key Project of Henan Educational Committee [14A150019, 14B150042, 15B610005, 15A150015]
- Science & Technology Innovation Talents in Universities of Henan Province [17HASTIT002]
- Program of Foundation and Frontier Technology Research of Henan Province [122300410296]
- Outstanding Young Talent Cultivation Project Funding of Henan Normal University [14YR002]
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A facile and direct oxidative reaction for the synthesis of vicinal tricarbonyl articles in moderate to excellent yields (53-88%) was developed starting from readily available beta-ketoamides in the presence of phenyliodine(III) bis-(trifluoroacetate). The resulting products possess significant synthetic potential, making this approach a valuable addition to the group of traditional methods already available for the preparation of these molecules.
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